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Intriguing mechanistic labyrinths in gold(<scp>i</scp>) catalysis

Carla Obradors,Antonio M. Echavarren

Cationic polymerization

Catalysis

Chemistry

2014

Many mechanistically intriguing reactions have been developed in the last decade using gold(I) as catalyst. Here we review the main mechanistic proposals in gold-catalysed activation of alkynes and allenes, in which this metal plays a central role by stabilising a variety of complex cationic intermediates.

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“Intriguing mechanistic labyrinths in gold(<scp>i</scp>) catalysis” is a paper by Carla Obradors Antonio M. Echavarren published in 2014. It has an Open Access status of “hybrid”. You can read and download a PDF Full Text of this paper here.