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Organoselenium-Catalyzed Mild Dehydration of Aldoximes: An Unexpected Practical Method for Organonitrile Synthesis

Lei Yu,Hongyan Li,Xu Zhang,Jianqing Ye,Jianping Liu,Qing Xu,Mark Lautens

Chemistry

Dehydration

Catalysis

2014

Areneselenenic acids (ArSeOH), readily generated from diaryl diselenides and H2O2 by in situ oxidation, were found to be effective and reusable catalysts for dehydration of aldoximes, leading to a practical and scalable preparation of useful organonitriles under mild conditions.

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“Organoselenium-Catalyzed Mild Dehydration of Aldoximes: An Unexpected Practical Method for Organonitrile Synthesis” is a paper by Lei Yu Hongyan Li Xu Zhang Jianqing Ye Jianping Liu Qing Xu Mark Lautens published in 2014. It has an Open Access status of “closed”. You can read and download a PDF Full Text of this paper here.