DOI: 10.1021/ol200744s

OpenAccess: Closed

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Palladium Catalyzed Alkoxy- and Aminocarbonylation of Vinyl Tosylates

Diana C. Reeves,Sonia Rodrı́guez,Heewon Lee,Nizar Haddad,Dhileepkumar Krishnamurthy,Chris H. Senanayake

Chemistry

Primary (astronomy)

Palladium

2011

The palladium catalyzed alkoxycarbonylation and aminocarbonylation of vinyl tosylates are described. A variety of ketone and aldehyde derived vinyl tosylates may be carbonylated in the presence of primary, secondary, and tertiary alcohols, or primary and secondary amines, to provide the corresponding esters and amides in good yields. The alkoxycarbonylation was applied to a short synthesis of isoguvacine.

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“Palladium Catalyzed Alkoxy- and Aminocarbonylation of Vinyl Tosylates” is a paper by Diana C. Reeves Sonia Rodrı́guez Heewon Lee Nizar Haddad Dhileepkumar Krishnamurthy Chris H. Senanayake published in 2011. It has an Open Access status of “closed”. You can read and download a PDF Full Text of this paper here.