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A Concise Approach to Paxilline Indole Diterpenes

David T. George,Eric J. Kuenstner,С. В. Пронин

Chemistry

Stereocenter

Indole test

2015

A synthetic approach to paxilline indole diterpenes is described. The route to the pentacyclic core relies on a new regioselective alkenylation of ketones and a tandem radical addition-aldol reaction sequence to access vicinal quaternary stereocenters. Emindole SB, the simplest member of the family, is synthesized in 11 steps from commercially available material to demonstrate the application of this approach.

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“A Concise Approach to Paxilline Indole Diterpenes” is a paper by David T. George Eric J. Kuenstner С. В. Пронин published in 2015. It has an Open Access status of “green”. You can read and download a PDF Full Text of this paper here.