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Pd-Catalyzed Stereoselective 1,2-Aryboration of Alkenylarenes

Penglin Zhang,Mimi Xing,Qitao Guan,Jinguo Zhang,Qian Zhao,Chun Zhang

Chemistry

Stereoselectivity

Enantioselective synthesis

2019

The palladium-catalyzed highly regio- and diastereoselective arylboration of alkenylarenes has been developed. This chemistry afforded the benzylic boronic esters with a broad substrate scope, which are valuable synthetic intermediates for organic synthesis. The chiral anion phase-transfer strategy was designed for this transformation to realize the regio-, diastereo-, and enantioselective control of this reaction simultaneously.

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“Pd-Catalyzed Stereoselective 1,2-Aryboration of Alkenylarenes” is a paper by Penglin Zhang Mimi Xing Qitao Guan Jinguo Zhang Qian Zhao Chun Zhang published in 2019. It has an Open Access status of “closed”. You can read and download a PDF Full Text of this paper here.