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Benzylic C–H Azidation Using the Zhdankin Reagent and a Copper Photoredox Catalyst

Pauline T. G. Rabet,Gabriele Fumagalli,Scott Boyd,Michael F. Greaney

Chemistry

Reagent

Copper

2016

An azidation method for C–N bond formation at benzylic C–H positions is described using copper-catalyzed visible light photochemistry and the Zhdankin azidoiodinane reagent. The method is applicable to a wide range of substrates bearing different functional groups and having a primary, secondary, or tertiary benzylic position, and is thought to proceed through a radical chain reaction.

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“Benzylic C–H Azidation Using the Zhdankin Reagent and a Copper Photoredox Catalyst” is a paper by Pauline T. G. Rabet Gabriele Fumagalli Scott Boyd Michael F. Greaney published in 2016. It has an Open Access status of “green”. You can read and download a PDF Full Text of this paper here.