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Ruthenium‐catalyzed [2+2+2] Cycloaddition of Diynes with Nitriles in Pure Water

Fen Xu,Chunxiang Wang,Xincheng Li,Boshun Wan

Ruthenium

Cycloaddition

Catalysis

2012

One ring to bind them: An efficient method for synthesizing highly functionalized pyridine derivatives from diynes and nitriles is described. The reaction system involves Cp*Ru(COD)Cl/tppts-catalyzed [2+2+2] cycloaddition in pure water. Without being accompanied by diyne dimerization or trimerization byproducts, the desired products can be obtained in moderate to high yields.

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“Ruthenium‐catalyzed [2+2+2] Cycloaddition of Diynes with Nitriles in Pure Water” is a paper by Fen Xu Chunxiang Wang Xincheng Li Boshun Wan published in 2012. It has an Open Access status of “closed”. You can read and download a PDF Full Text of this paper here.