Design of a Highly Active Ir/Fe(OH)_<i>x</i> Catalyst: Versatile Application of Pt‐Group Metals for the Preferential Oxidation of Carbon Monoxide

Angewandte Chemie International EditionVolume 51, Issue 12 p. 2920-2924 Communication Design of a Highly Active Ir/Fe(OH)x Catalyst: Versatile Application of Pt-Group Metals for the Preferential Oxidation of Carbon Monoxide† Dr. Jian Lin, Dr. Jian Lin State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China) http://www.taozhang.dicp.ac.cn/ These authors contributed equally to this work.Search for more papers by this authorDr. Botao Qiao, Dr. Botao Qiao State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China) http://www.taozhang.dicp.ac.cn/ These authors contributed equally to this work.Search for more papers by this authorProf. Dr. Jingyue Liu, Prof. Dr. Jingyue Liu Center for Nanoscience, Department of Physics & Astronomy and Department of Chemistry and Biochemistry, University of Missouri-St. Louis, One University Boulevard, St. Louis, MO 63121 (USA)Search for more papers by this authorDr. Yanqiang Huang, Dr. Yanqiang Huang State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China) http://www.taozhang.dicp.ac.cn/Search for more papers by this authorProf. Dr. Aiqin Wang, Prof. Dr. Aiqin Wang State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China) http://www.taozhang.dicp.ac.cn/Search for more papers by this authorDr. Lin Li, Dr. Lin Li State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China) http://www.taozhang.dicp.ac.cn/Search for more papers by this authorDr. Wansheng Zhang, Dr. Wansheng Zhang State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China) http://www.taozhang.dicp.ac.cn/Search for more papers by this authorDr. Lawrence F. Allard, Dr. Lawrence F. Allard Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (USA)Search for more papers by this authorProf. Dr. Xiaodong Wang, Corresponding Author Prof. Dr. Xiaodong Wang [email protected] State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China) http://www.taozhang.dicp.ac.cn/State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China) http://www.taozhang.dicp.ac.cn/Search for more papers by this authorProf. Dr. Tao Zhang, Corresponding Author Prof. Dr. Tao Zhang [email protected] State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China) http://www.taozhang.dicp.ac.cn/State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China) http://www.taozhang.dicp.ac.cn/Search for more papers by this author Dr. Jian Lin, Dr. Jian Lin State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China) http://www.taozhang.dicp.ac.cn/ These authors contributed equally to this work.Search for more papers by this authorDr. Botao Qiao, Dr. Botao Qiao State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China) http://www.taozhang.dicp.ac.cn/ These authors contributed equally to this work.Search for more papers by this authorProf. Dr. Jingyue Liu, Prof. Dr. Jingyue Liu Center for Nanoscience, Department of Physics & Astronomy and Department of Chemistry and Biochemistry, University of Missouri-St. Louis, One University Boulevard, St. Louis, MO 63121 (USA)Search for more papers by this authorDr. Yanqiang Huang, Dr. Yanqiang Huang State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China) http://www.taozhang.dicp.ac.cn/Search for more papers by this authorProf. Dr. Aiqin Wang, Prof. Dr. Aiqin Wang State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China) http://www.taozhang.dicp.ac.cn/Search for more papers by this authorDr. Lin Li, Dr. Lin Li State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China) http://www.taozhang.dicp.ac.cn/Search for more papers by this authorDr. Wansheng Zhang, Dr. Wansheng Zhang State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China) http://www.taozhang.dicp.ac.cn/Search for more papers by this authorDr. Lawrence F. Allard, Dr. Lawrence F. Allard Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (USA)Search for more papers by this authorProf. Dr. Xiaodong Wang, Corresponding Author Prof. Dr. Xiaodong Wang [email protected] State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China) http://www.taozhang.dicp.ac.cn/State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China) http://www.taozhang.dicp.ac.cn/Search for more papers by this authorProf. Dr. Tao Zhang, Corresponding Author Prof. Dr. Tao Zhang [email protected] State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China) http://www.taozhang.dicp.ac.cn/State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China) http://www.taozhang.dicp.ac.cn/Search for more papers by this author First published: 03 February 2012 https://doi.org/10.1002/anie.201106702Citations: 174 † Financial supports for this research work from the NSF of China (grant numbers 20803079, 21003119, 21076211, and 21103173). The electron microscopy work was conducted at the Oak Ridge National Laboratory′s High Temperature Materials Laboratory, sponsored by the U. S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Vehicle Technologies Program. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract With the right support: A Ir/Fe(OH)x catalyst was designed. The Fe(OH)x support stabilizes the metal catalyst used for the oxidation of carbon monoxide. The catalyst was highly active for the oxidation of carbon monoxide in the presence of excess hydrogen at room temperature and showed a wide temperature range for the total conversion of CO (see picture). Supporting Information Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_201106702_sm_miscellaneous_information.pdf554.1 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1C. Song, Catal. Today 2002, 77, 17–49. 2 2aV. A. Goltsov, T. N. Veziroglu, Int. J. Hydrogen Energy 2001, 26, 909–915; 2bS. Jiménez, J. Soler, R. X. Valenzuela, L. Daza, J. 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Citing Literature Volume51, Issue12March 19, 2012Pages 2920-2924 ReferencesRelatedInformation